Carbonyl‐olefin metathesis reactions have emerged as an invaluable strategy for the direct formation of carbon–carbon bonds, enabling the efficient construction of complex molecular architectures.
Chiral tetrahydro-β-carbolines or tryptolines that contain a tetrasubstituted carbon center provides a framework for a variety of biologically active compounds. This basic structure is found in ...
Scientists at Scripps Research have used rapid alternating current (AC) to selectively reduce carbonyl groups (J. Am. Chem. Soc. 2021, DOI: 10.1021/jacs.1c06572). The technique avoids side reactions ...
Carbonyls (C=O groups) are popular reactive handles. But carbonylation reactions, which create these useful groups by appending carbon monoxide to aryl halides or alkyl halides with the help of a ...
Imines are one of several reactive groups, called functional groups, that are present in a compound. The mechanism by which the compound reacts is attributed to the properties of its functional group.
Rearranging the parts of a molecule is like rearranging the contents of a tightly packed suitcase: You must go through a number of steps, taking objects in and out to get the configuration you want. A ...
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